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Orihime's brother turns into a hollow, he believes that Orihime has forgotten all about him since she stopped her daily praying for him. First, he blamed both Tatsuki and Ichigo for tearing them apart, then he blames Orihime herself as she is the one that turned him into a hollow in the first place. So, as he tries to kill Orihime, Ichigo shortly comes to the rescue. Here's what he says about big brothers!
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Hope you like

reference: bleach manga chapters 2 and 5 (mainly ch 5)