1st Division; Captain Yamamoto Genryuusai Shigekuni
First Division Captain and founder of the shinigami academy. By virtue of his position and seniority, he is also the supreme commander of the Gotei 13.
Yamamoto-taicho looks like a very old man, almost after the fashion of the Taoist Immortals, but under his shinigami robes he still has a strong body that has not decayed with age. His spiritual pressure is possibly greater than any other being in Soul Society; it was enough to paralyze Ise Nanao--the Eighth Division Vice-Captain--with a mere glance. He wields Ryuujin Jakka, the strongest of all fire-type zanpaku-to. His skill in kidou is unknown, but probably as formidable as his swordsmanship, as he appears to embody the convention of the "old master."
Kyouraku Shunsui 8th Division Captain and Ukitake Juushiro 13th Division Captain seem to have a particularly strong relationship with Yamamoto-taicho. He mentions that they were the first graduates of his shinigami academy to rise to the rank of captain, and some clips from the anime show Yamamoto-taicho sparring with the two and easily winning.